Možná vám to pomůže.
SELECT SUBSTRING(myColumn, 1, CASE CHARINDEX('/', myColumn)
WHEN 0
THEN LEN(myColumn)
ELSE CHARINDEX('/', myColumn) - 1
END) AS FirstName
,SUBSTRING(myColumn, CASE CHARINDEX('/', myColumn)
WHEN 0
THEN LEN(myColumn) + 1
ELSE CHARINDEX('/', myColumn) + 1
END, 1000) AS LastName
FROM MyTable